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Organic Chemistry
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AS Organic Chemistry Past Papers (200 Questions Solved)
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Chemical Equilibria
Chemical Equilibria Outline Introduction to Chemical Equilibria Definition of chemical equilibrium Characteristics of a system in equilibrium Dynamic nature of equilibrium The Equilibrium Constant (Kc) Derivation and expression of the equilibrium constant Calculation of Kc for homogeneous and heterogeneous equilibria Units of Kc and their significance Factors Affecting Equilibrium Le Chatelier's Principle Effect of changes in concentration, temperature, and pressure on equilibrium Effect of catalysts on equilibrium position Applications of Equilibrium Principles Industrial processes (Haber Process, Contact Process) Biological systems and biochemical equilibria Environmental equilibria (acid rain, ocean acidification) Calculation of Equilibrium Concentrations Using the ICE (Initial, Change, Equilibrium) table method Solving equilibrium problems involving Kc Relationship Between Kp and Kc Definition of Kp (equilibrium constant for gaseous systems) Conversion between Kc and Kp Impact of partial pressure on equilibrium
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Chemical Equilibria Overview

In chemistry, a chemical equilibrium is a state in which the concentrations of reactants and products remain constant over time. This happens when the rates of the forward and reverse reactions are equal. This equilibrium state can be represented using the equilibrium constant (K), which is a ratio of the concentrations of the products to the reactants, each raised to the power of their respective coefficients from the balanced chemical equation.

Key Concepts:

  1. Dynamic Equilibrium: Chemical equilibria are dynamic, meaning that while the concentrations of reactants and products remain constant, the reactions continue to occur in both directions at the same rate.

  2. Equilibrium Constant (K): The equilibrium constant is a numerical value that indicates the ratio of product concentrations to reactant concentrations at equilibrium. For a general reaction aA+bB↔cC+dDaA + bB leftrightarrow cC + dD, the equilibrium constant expression is:

[ K = frac{[C]c[D]d}{[A]a[B]b} ]

Here, [A][A], [B][B], [C][C], and [D][D] represent the concentrations of the respective species.

  1. Le Chatelier’s Principle: This principle states that if a system at equilibrium is subjected to a change in concentration, temperature, or pressure, the system will adjust to partially counteract the change and restore a new equilibrium.

  2. Reaction Quotient (Q): The reaction quotient has the same form as the equilibrium constant expression but is used to determine the direction in which a reaction will proceed to reach equilibrium. If Q<KQ < K, the reaction will proceed in the forward direction; if Q>KQ > K, the reaction will proceed in the reverse direction.

Example Reaction: Consider the synthesis of ammonia (NH₃) via the Haber process:

N2(g)+3H2(g)↔2NH3(g)N_2(g) + 3H_2(g) leftrightarrow 2NH_3(g)

The equilibrium constant expression for this reaction is:

[ K = frac{[NH_3]2}{[N_2][H_2]3} ]

Importance of Equilibria: Understanding chemical equilibria is crucial in industrial processes, biological systems, and environmental science, as it helps in predicting the concentrations of reactants and products under different conditions and optimizing reactions for maximum yield.

 

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